Names | |
---|---|
Preferred IUPAC name
Potassium fluorosilicate | |
Other names
Potassium hexafluorosilicate(IV)
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
ECHA InfoCard | 100.037.163 |
EC Number |
|
PubChem
CID
|
|
RTECS number |
|
UNII | |
UN number | 2655 |
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
K2[SiF6 | |
Molar mass | 220.28 gmol−1 [1] |
Density | 2.27gcm−3, [1] 2.719gcm−3 [2] |
Slightly soluble in water | |
Structure | |
cubic | |
Fm3m | |
a = 0.8134 nm
| |
Lattice volume (V)
|
0.538.2 nm3 |
Formula units (Z)
|
4 |
Hazards | |
GHS labelling: | |
![]() | |
Danger | |
H301, H311, H331 | |
P261, P264, P270, P271, P280, P301+P310, P302+P352, P304+P340, P311, P312, P321, P322, P330, P361, P363, P403+P233, P405, P501 | |
Related compounds | |
Other
cations
|
Ammonium hexafluorosilicate Sodium fluorosilicate |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Potassium fluorosilicate is a chemical compound with the chemical formula K2[SiF6.
When doped with Potassium hexafluoromanganate(IV) ((K2[MnF6) it forms a narrow band red producing phosphor, (often abbreviated PSF or KSF), of economic interest due to its applicability in LED lighting and displays.
Occurs naturally as Hiereatite, found in the Aeolian islands (Sicily/Italy). [3] A hexagonal form Demartinite has also been found at the rim of volcanic fumaroles in the same islands. [4]
According to analysis by (Loehlin, 1984) it has space group Fm3m, with a0 = 0.8134 nm, V = 0.538.2 nm3 at 295K. The Si-F bond length is 0.1683 nm. [2] At high temperatures and pressures -beta and -gamma phases exist. [5]
Potassium fluorosilicate has applications in porcelain manufacture, the preservation of timber, aluminium and magnesium smelting, and the manufacture of optical glass. [1]
When doped with potassium hexafluoromanganate(IV) (K2[MnF6), a narrow band red phosphor is produced, emitting at around 630 nm. This substance has application improving the white light quality of white LEDs that use a blue emitting LED in combination with the yellow cerium doped yttrium aluminium garnet phosphor (YAG), Y3Al5O12:Ce3+. [6]
Synthesis routes to the phosphor include co-crystallisation and co-precipitation. For example, K2[MnF6 in (40%) hydrofluoric acid with potassium fluoride can be mixed with SiO2 dissolved in (40%) hydrofluoric acid to co-precipitate the phosphor. [5]
The acronyms KSF or PSF are used for potassium fluorosilicate phosphors. [7]
Names | |
---|---|
Preferred IUPAC name
Potassium fluorosilicate | |
Other names
Potassium hexafluorosilicate(IV)
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
ECHA InfoCard | 100.037.163 |
EC Number |
|
PubChem
CID
|
|
RTECS number |
|
UNII | |
UN number | 2655 |
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
K2[SiF6 | |
Molar mass | 220.28 gmol−1 [1] |
Density | 2.27gcm−3, [1] 2.719gcm−3 [2] |
Slightly soluble in water | |
Structure | |
cubic | |
Fm3m | |
a = 0.8134 nm
| |
Lattice volume (V)
|
0.538.2 nm3 |
Formula units (Z)
|
4 |
Hazards | |
GHS labelling: | |
![]() | |
Danger | |
H301, H311, H331 | |
P261, P264, P270, P271, P280, P301+P310, P302+P352, P304+P340, P311, P312, P321, P322, P330, P361, P363, P403+P233, P405, P501 | |
Related compounds | |
Other
cations
|
Ammonium hexafluorosilicate Sodium fluorosilicate |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Potassium fluorosilicate is a chemical compound with the chemical formula K2[SiF6.
When doped with Potassium hexafluoromanganate(IV) ((K2[MnF6) it forms a narrow band red producing phosphor, (often abbreviated PSF or KSF), of economic interest due to its applicability in LED lighting and displays.
Occurs naturally as Hiereatite, found in the Aeolian islands (Sicily/Italy). [3] A hexagonal form Demartinite has also been found at the rim of volcanic fumaroles in the same islands. [4]
According to analysis by (Loehlin, 1984) it has space group Fm3m, with a0 = 0.8134 nm, V = 0.538.2 nm3 at 295K. The Si-F bond length is 0.1683 nm. [2] At high temperatures and pressures -beta and -gamma phases exist. [5]
Potassium fluorosilicate has applications in porcelain manufacture, the preservation of timber, aluminium and magnesium smelting, and the manufacture of optical glass. [1]
When doped with potassium hexafluoromanganate(IV) (K2[MnF6), a narrow band red phosphor is produced, emitting at around 630 nm. This substance has application improving the white light quality of white LEDs that use a blue emitting LED in combination with the yellow cerium doped yttrium aluminium garnet phosphor (YAG), Y3Al5O12:Ce3+. [6]
Synthesis routes to the phosphor include co-crystallisation and co-precipitation. For example, K2[MnF6 in (40%) hydrofluoric acid with potassium fluoride can be mixed with SiO2 dissolved in (40%) hydrofluoric acid to co-precipitate the phosphor. [5]
The acronyms KSF or PSF are used for potassium fluorosilicate phosphors. [7]