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| Names | |
|---|---|
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IUPAC name
Uranium fluoride oxide
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| Other names
Uranium oxyfluoride
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| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.033.529 |
| EC Number |
|
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
| Properties | |
| UO2F2 | |
| Molar mass | 308.02 g/mol |
| Melting point | Decomposes @ 300 °C |
| Boiling point | Sublimes |
| Solubility in other solvents | VS |
| Hazards | |
| GHS labelling: | |
| |
| Danger | |
| H300, H330, H373, H411 | |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Uranyl fluoride is the inorganic compound with the formula UO2F2. As shown by x-ray crystallography, the uranyl (UO22+) centers are complemented by six fluoride ligands. [1]
This salt is very soluble in water as well as hygroscopic. It is formed in the hydrolysis of uranium hexafluoride (UF6):
- UF6 + 2 H2O → UO2F2 + 4 HF
It can also be formed in the hydrofluorination of uranium trioxide (UO3):
- UO3 + 2 HF → UO2F2 + H2O [2]
References
- ^ Zachariasen, W. H. (1948). "Crystal chemical studies of the 5f-series of elements. III. A study of the disorder in the crystal structure of anhydrous uranyl fluoride". Acta Crystallographica. 1 (6): 277–281. Bibcode: 1948AcCry...1..277Z. doi: 10.1107/S0365110X48000764.
- ^ Jang, Harry; Louis-Jean, James; Poineau, Frederic (2023-06-20). "Synthesis and Morphological Control of UO2F2 Particulates". ACS Omega. 8 (24): 21996–22002. doi: 10.1021/acsomega.3c01999. ISSN 2470-1343. PMC 10286299. PMID 37360455.
 | This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |
|
| |
| Names | |
|---|---|
|
IUPAC name
Uranium fluoride oxide
| |
| Other names
Uranium oxyfluoride
| |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.033.529 |
| EC Number |
|
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
| Properties | |
| UO2F2 | |
| Molar mass | 308.02 g/mol |
| Melting point | Decomposes @ 300 °C |
| Boiling point | Sublimes |
| Solubility in other solvents | VS |
| Hazards | |
| GHS labelling: | |
|
| |
| Danger | |
| H300, H330, H373, H411 | |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Uranyl fluoride is the inorganic compound with the formula UO2F2. As shown by x-ray crystallography, the uranyl (UO22+) centers are complemented by six fluoride ligands. [1]
This salt is very soluble in water as well as hygroscopic. It is formed in the hydrolysis of uranium hexafluoride (UF6):
- UF6 + 2 H2O → UO2F2 + 4 HF
It can also be formed in the hydrofluorination of uranium trioxide (UO3):
- UO3 + 2 HF → UO2F2 + H2O [2]
References
- ^ Zachariasen, W. H. (1948). "Crystal chemical studies of the 5f-series of elements. III. A study of the disorder in the crystal structure of anhydrous uranyl fluoride". Acta Crystallographica. 1 (6): 277–281. Bibcode: 1948AcCry...1..277Z. doi: 10.1107/S0365110X48000764.
- ^ Jang, Harry; Louis-Jean, James; Poineau, Frederic (2023-06-20). "Synthesis and Morphological Control of UO2F2 Particulates". ACS Omega. 8 (24): 21996–22002. doi: 10.1021/acsomega.3c01999. ISSN 2470-1343. PMC 10286299. PMID 37360455.
|
| This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |