From Wikipedia, the free encyclopedia
Methanetellurol
Identifiers
3D model ( JSmol)
ChemSpider
PubChem CID
  • InChI=1S/CH4Te/c1-2/h2H,1H3
    Key: JNLXBRURJAYDTD-UHFFFAOYSA-N
  • C[TeH]
Properties
CH3TeH
Molar mass 143.64 g·mol−1
Appearance colorless gas
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Methanetellurol is the organotellurium compound with the formula C H3 TeH. It is the simplest organotellurium compound that has been purified in bulk. It is classified as a tellurol. A colorless gas, it decomposes to Te and methane near room temperature. It is prepared by reduction of dimethyl ditelluride using Na/ NH3 followed by protonation of the CH3TeNa+ (sodium methanetellurolate) with sulfuric acid. [1] Few publications describe this compound as a consequence of its instability and paucity of applications.

According to IR spectroscopy, νTe-H = 1995 cm−1. For the lighter homologues, νE-H = 2342 (E = Se), 2606 (E = S), and 3710 cm−1 (E = O) for methaneselenol, methanethiol, and methanol. [1]

References

  1. ^ a b Hamada, K.; Morishita, H. (1977). "The Synthesis and the Raman and Infrared Spectra of Methanetellurol". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 7 (4): 355–366. doi: 10.1080/00945717708069709.
From Wikipedia, the free encyclopedia
Methanetellurol
Identifiers
3D model ( JSmol)
ChemSpider
PubChem CID
  • InChI=1S/CH4Te/c1-2/h2H,1H3
    Key: JNLXBRURJAYDTD-UHFFFAOYSA-N
  • C[TeH]
Properties
CH3TeH
Molar mass 143.64 g·mol−1
Appearance colorless gas
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Methanetellurol is the organotellurium compound with the formula C H3 TeH. It is the simplest organotellurium compound that has been purified in bulk. It is classified as a tellurol. A colorless gas, it decomposes to Te and methane near room temperature. It is prepared by reduction of dimethyl ditelluride using Na/ NH3 followed by protonation of the CH3TeNa+ (sodium methanetellurolate) with sulfuric acid. [1] Few publications describe this compound as a consequence of its instability and paucity of applications.

According to IR spectroscopy, νTe-H = 1995 cm−1. For the lighter homologues, νE-H = 2342 (E = Se), 2606 (E = S), and 3710 cm−1 (E = O) for methaneselenol, methanethiol, and methanol. [1]

References

  1. ^ a b Hamada, K.; Morishita, H. (1977). "The Synthesis and the Raman and Infrared Spectra of Methanetellurol". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 7 (4): 355–366. doi: 10.1080/00945717708069709.

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