| Identifiers | |
|---|---|
3D model (
JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.204.020 |
PubChem
CID
|
|
| |
| |
| Properties | |
| BiSb | |
| Molar mass | 330.74 g/mol |
| Appearance | Faint-grey to dark-grey powder |
| Density | 8.31 g/cm3 |
| Solubility | insoluble |
| Structure | |
| Hexagonal, A7, SpaceGroup = R-3m, No. 166 | |
a = 4.546A, c = 11.860A
[1]
| |
| Hazards | |
| GHS labelling: | |
| |
| Warning | |
| H302, H332, H411 | |
| NFPA 704 (fire diamond) | |
| Safety data sheet (SDS) | [1] |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Bismuth antimonides, Bismuth-antimonys, or Bismuth-antimony alloys, (Bi1−xSbx) are binary alloys of bismuth and antimony in various ratios.
Some, in particular Bi0.9Sb0.1, were the first experimentally-observed three-dimensional topological insulators, materials that have conducting surface states but have an insulating interior. [2]
Various BiSb alloys also superconduct at low temperatures, [3] are semiconductors, [1] and are used in thermoelectric devices. [4]
Bismuth antimonide itself (see box to right) is sometimes described as Bi2Sb2. [5]
Synthesis
Crystals of bismuth antimonides are synthesized by melting bismuth and antimony together under inert gas or vacuum. Zone melting is used to decrease the concentration of impurities. [4] When synthesizing single crystals of bismuth antimonides, it is important that impurities are removed from the samples, as oxidation occurring at the impurities leads to polycrystalline growth. [1]
Properties
Topological insulator
Pure bismuth is a semimetal, containing a small band gap, which leads to it having a relatively high conductivity (7.7×105 S/m at 20 °C). When the bismuth is doped with antimony, the conduction band decreases in energy and the valence band increases in energy. At an antimony concentration of 4%, the two bands intersect, forming a Dirac point [2] (which is defined as a point where the conduction and valence bands intersect). Further increases in the concentration of antimony result in a band inversion, in which the energy of the valence band becomes greater than that of the conduction band at specific momenta. Between Sb concentrations of 7 and 22%, the bands no longer intersect, and the Bi1−xSbx becomes an inverted-band insulator. [6] It is at these higher concentrations of Sb that the band gap in the surface states vanishes, and the material thus conducts at its surface. [2]
Superconductor
The highest temperatures at which Bi0.4Sb0.6, as a thin film of thicknesses 150–1350 Å, superconducts (the critical temperature Tc) is approximately 2 K. [3] Single crystal Bi0.935Sb0.065 can superconduct at slightly higher temperatures, and at 4.2 K, its critical magnetic field Bc (the maximum magnetic field that the superconductor can expel) of 1.6 T at 4.2 K. [7]
Semiconductor
Electron mobility is one important parameter describing semiconductors because it describes the rate at which electrons can travel through the semiconductor. At 40 K, electron mobility ranged from 4.9×105 cm2/V·s at an antimony concentration of 0 to 2.4×105 cm2/V·s at an antimony concentration of 7.2%. [1] This is much greater than the electron mobility of other common semiconductors like silicon, which is 1400 cm2/V·s at room temperature. [8]
Another important parameter of Bi1−xSbx is the effective electron mass (EEM), a measure of the ratio of the acceleration of an electron to the force applied to an electron. The effective electron mass is 2×10−3 me for x = 0.11 and 9×10−4 me at x = 0.06. [2] This is much less than the electron effective mass in many common semiconductors (1.09 in Si at 300 K, 0.55 in Ge, and 0.067 in GaAs). A low EEM is good for Thermophotovoltaic applications.
Thermoelectric
Bismuth antimonides are used as the n-type legs in many thermoelectric devices below room temperature. The thermoelectric efficiency, given by its figure of merit zT = σS2T/λ, where S is the Seebeck coefficient, λ is the thermal conductivity, and σ is the electrical conductivity, describes the ratio of the energy provided by the thermoelectric to the heat absorbed by the device. At 80 K, the figure of merit (zT) for Bi1−xSbx peaks at 6.5×10−3 K−1 when x = 0.15. [4] Also, the Seebeck coefficient (the ratio of the potential difference between ends of a material to the temperature difference between the sides) at 80 K of Bi0.9Sb0.1 is −140 μV/K, much lower than the Seebeck coefficient of pure bismuth, −50 μV/K. [9]
References
- ^ a b c d Jain, A. L. (1959). "Temperature Dependence of the Electrical Properties of Bismuth-Antimony Alloys". Physical Review. 114 (6): 1518–1528. Bibcode: 1959PhRv..114.1518J. doi: 10.1103/physrev.114.1518.
- ^ a b c d Hsieh, D.; Qian, D.; Wray, L.; Xia, Y.; Hor, Y. S.; Cava, R. J.; Hasan, M. Z. (2008-04-24). "A topological Dirac insulator in a quantum spin Hall phase". Nature. 452 (7190): 970–974. arXiv: 0902.1356. Bibcode: 2008Natur.452..970H. doi: 10.1038/nature06843. ISSN 0028-0836. PMID 18432240. S2CID 4402113.
- ^ a b Zally, G. D.; Mochel, J. M. (1971). "Fluctuation Heat Capacity in Superconducting Thin Films of Amorphous BiSb". Physical Review Letters. 27 (25): 1710–1712. Bibcode: 1971PhRvL..27.1710Z. doi: 10.1103/physrevlett.27.1710.
- ^ a b c Smith, G. E.; Wolfe, R. (1962-03-01). "Thermoelectric Properties of Bismuth-Antimony Alloys". Journal of Applied Physics. 33 (3): 841–846. Bibcode: 1962JAP....33..841S. doi: 10.1063/1.1777178. ISSN 0021-8979.
- ^ PubChem. "Bismuth, compd. with antimony (1:1)". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-06-15.
- ^ Shuichi Murakami (2007). "Phase transition between the quantum spin Hall and insulator phases in 3D: emergence of a topological gapless phase". New Journal of Physics. 9 (9): 356. arXiv: 0710.0930. Bibcode: 2007NJPh....9..356M. doi: 10.1088/1367-2630/9/9/356. S2CID 13999448.
- ^ Kasumov, A. Yu.; Kononenko, O. V.; Matveev, V. N.; Borsenko, T. B.; Tulin, V. A.; Vdovin, E. E.; Khodos, I. I. (1996). "Anomalous Proximity Effect in the Nb–BiSb–Nb Junctions". Physical Review Letters. 77 (14): 3029–3032. Bibcode: 1996PhRvL..77.3029K. doi: 10.1103/physrevlett.77.3029. PMID 10062113.
- ^ "Electrical properties of Silicon (Si)". www.ioffe.rssi.ru. Retrieved 2015-12-11.
- ^ Goldsmid, H. J. (1970-01-16). "Bismuth–antimony alloys". Physica Status Solidi A. 1 (1): 7–28. Bibcode: 1970PSSAR...1....7G. doi: 10.1002/pssa.19700010102. ISSN 1521-396X.
| Identifiers | |
|---|---|
3D model (
JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.204.020 |
PubChem
CID
|
|
| |
| |
| Properties | |
| BiSb | |
| Molar mass | 330.74 g/mol |
| Appearance | Faint-grey to dark-grey powder |
| Density | 8.31 g/cm3 |
| Solubility | insoluble |
| Structure | |
| Hexagonal, A7, SpaceGroup = R-3m, No. 166 | |
a = 4.546A, c = 11.860A
[1]
| |
| Hazards | |
| GHS labelling: | |
|
| |
| Warning | |
| H302, H332, H411 | |
| NFPA 704 (fire diamond) | |
| Safety data sheet (SDS) | [1] |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Bismuth antimonides, Bismuth-antimonys, or Bismuth-antimony alloys, (Bi1−xSbx) are binary alloys of bismuth and antimony in various ratios.
Some, in particular Bi0.9Sb0.1, were the first experimentally-observed three-dimensional topological insulators, materials that have conducting surface states but have an insulating interior. [2]
Various BiSb alloys also superconduct at low temperatures, [3] are semiconductors, [1] and are used in thermoelectric devices. [4]
Bismuth antimonide itself (see box to right) is sometimes described as Bi2Sb2. [5]
Synthesis
Crystals of bismuth antimonides are synthesized by melting bismuth and antimony together under inert gas or vacuum. Zone melting is used to decrease the concentration of impurities. [4] When synthesizing single crystals of bismuth antimonides, it is important that impurities are removed from the samples, as oxidation occurring at the impurities leads to polycrystalline growth. [1]
Properties
Topological insulator
Pure bismuth is a semimetal, containing a small band gap, which leads to it having a relatively high conductivity (7.7×105 S/m at 20 °C). When the bismuth is doped with antimony, the conduction band decreases in energy and the valence band increases in energy. At an antimony concentration of 4%, the two bands intersect, forming a Dirac point [2] (which is defined as a point where the conduction and valence bands intersect). Further increases in the concentration of antimony result in a band inversion, in which the energy of the valence band becomes greater than that of the conduction band at specific momenta. Between Sb concentrations of 7 and 22%, the bands no longer intersect, and the Bi1−xSbx becomes an inverted-band insulator. [6] It is at these higher concentrations of Sb that the band gap in the surface states vanishes, and the material thus conducts at its surface. [2]
Superconductor
The highest temperatures at which Bi0.4Sb0.6, as a thin film of thicknesses 150–1350 Å, superconducts (the critical temperature Tc) is approximately 2 K. [3] Single crystal Bi0.935Sb0.065 can superconduct at slightly higher temperatures, and at 4.2 K, its critical magnetic field Bc (the maximum magnetic field that the superconductor can expel) of 1.6 T at 4.2 K. [7]
Semiconductor
Electron mobility is one important parameter describing semiconductors because it describes the rate at which electrons can travel through the semiconductor. At 40 K, electron mobility ranged from 4.9×105 cm2/V·s at an antimony concentration of 0 to 2.4×105 cm2/V·s at an antimony concentration of 7.2%. [1] This is much greater than the electron mobility of other common semiconductors like silicon, which is 1400 cm2/V·s at room temperature. [8]
Another important parameter of Bi1−xSbx is the effective electron mass (EEM), a measure of the ratio of the acceleration of an electron to the force applied to an electron. The effective electron mass is 2×10−3 me for x = 0.11 and 9×10−4 me at x = 0.06. [2] This is much less than the electron effective mass in many common semiconductors (1.09 in Si at 300 K, 0.55 in Ge, and 0.067 in GaAs). A low EEM is good for Thermophotovoltaic applications.
Thermoelectric
Bismuth antimonides are used as the n-type legs in many thermoelectric devices below room temperature. The thermoelectric efficiency, given by its figure of merit zT = σS2T/λ, where S is the Seebeck coefficient, λ is the thermal conductivity, and σ is the electrical conductivity, describes the ratio of the energy provided by the thermoelectric to the heat absorbed by the device. At 80 K, the figure of merit (zT) for Bi1−xSbx peaks at 6.5×10−3 K−1 when x = 0.15. [4] Also, the Seebeck coefficient (the ratio of the potential difference between ends of a material to the temperature difference between the sides) at 80 K of Bi0.9Sb0.1 is −140 μV/K, much lower than the Seebeck coefficient of pure bismuth, −50 μV/K. [9]
References
- ^ a b c d Jain, A. L. (1959). "Temperature Dependence of the Electrical Properties of Bismuth-Antimony Alloys". Physical Review. 114 (6): 1518–1528. Bibcode: 1959PhRv..114.1518J. doi: 10.1103/physrev.114.1518.
- ^ a b c d Hsieh, D.; Qian, D.; Wray, L.; Xia, Y.; Hor, Y. S.; Cava, R. J.; Hasan, M. Z. (2008-04-24). "A topological Dirac insulator in a quantum spin Hall phase". Nature. 452 (7190): 970–974. arXiv: 0902.1356. Bibcode: 2008Natur.452..970H. doi: 10.1038/nature06843. ISSN 0028-0836. PMID 18432240. S2CID 4402113.
- ^ a b Zally, G. D.; Mochel, J. M. (1971). "Fluctuation Heat Capacity in Superconducting Thin Films of Amorphous BiSb". Physical Review Letters. 27 (25): 1710–1712. Bibcode: 1971PhRvL..27.1710Z. doi: 10.1103/physrevlett.27.1710.
- ^ a b c Smith, G. E.; Wolfe, R. (1962-03-01). "Thermoelectric Properties of Bismuth-Antimony Alloys". Journal of Applied Physics. 33 (3): 841–846. Bibcode: 1962JAP....33..841S. doi: 10.1063/1.1777178. ISSN 0021-8979.
- ^ PubChem. "Bismuth, compd. with antimony (1:1)". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-06-15.
- ^ Shuichi Murakami (2007). "Phase transition between the quantum spin Hall and insulator phases in 3D: emergence of a topological gapless phase". New Journal of Physics. 9 (9): 356. arXiv: 0710.0930. Bibcode: 2007NJPh....9..356M. doi: 10.1088/1367-2630/9/9/356. S2CID 13999448.
- ^ Kasumov, A. Yu.; Kononenko, O. V.; Matveev, V. N.; Borsenko, T. B.; Tulin, V. A.; Vdovin, E. E.; Khodos, I. I. (1996). "Anomalous Proximity Effect in the Nb–BiSb–Nb Junctions". Physical Review Letters. 77 (14): 3029–3032. Bibcode: 1996PhRvL..77.3029K. doi: 10.1103/physrevlett.77.3029. PMID 10062113.
- ^ "Electrical properties of Silicon (Si)". www.ioffe.rssi.ru. Retrieved 2015-12-11.
- ^ Goldsmid, H. J. (1970-01-16). "Bismuth–antimony alloys". Physica Status Solidi A. 1 (1): 7–28. Bibcode: 1970PSSAR...1....7G. doi: 10.1002/pssa.19700010102. ISSN 1521-396X.