Identifiers | |
---|---|
ECHA InfoCard | 100.021.982 |
CompTox Dashboard (
EPA)
|
|
Properties | |
C24H40O32Zr6 | |
Molar mass | 1387.896 g·mol−1 |
Appearance | white solid |
soluble | |
Related compounds | |
Related compounds
|
zirconium dioxide, zirconium(IV) chloride |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Zirconium acetate usually refers to the chemical formula Zr6O4(OH)4(O2CCH3)12. It forms by the reaction of zirconyl chloride and acetate. Claims of Zr(O2CCH3)4 [1] have been superseded by experiments using X-ray crystallography. [2]
The species Zr6O4(OH)4(O2CCH3)12 is a common precursor to metal-organic frameworks (MOFs). [3]
https://doi.org/10.1021/acs.inorgchem.6b01624 Copyright © 2017 American Chemical Society RIGHTS & PERMISSIONS Subscribed Access Article Views 3592 Altmetric 5 Citations 57 LEARN ABOUT THESE METRICS Share
Add to
Export
RIS PDF (2 MB) OpenURL UNIV ILLINOIS URBANA-CHAMPAIGNSupporting Info (2)»Supporting Information SUBJECTS:Cluster chemistry, Go to Inorganic Chemistry Inorganic Chemistry Abstract
Complex formation and the coordination of zirconium with acetic acid were investigated with Zr K-edge extended X-ray absorption fine structure spectroscopy (EXAFS) and single-crystal diffraction. Zr K-edge EXAFS spectra show that a stepwise increase of acetic acid in aqueous solution with 0.1 M Zr(IV) leads to a structural rearrangement from initial tetranuclear hydrolysis species [Zr4(OH)8(OH2)16]8+ to a hexanuclear acetate species Zr6(O)4(OH)4(CH3COO)12.
Identifiers | |
---|---|
ECHA InfoCard | 100.021.982 |
CompTox Dashboard (
EPA)
|
|
Properties | |
C24H40O32Zr6 | |
Molar mass | 1387.896 g·mol−1 |
Appearance | white solid |
soluble | |
Related compounds | |
Related compounds
|
zirconium dioxide, zirconium(IV) chloride |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Zirconium acetate usually refers to the chemical formula Zr6O4(OH)4(O2CCH3)12. It forms by the reaction of zirconyl chloride and acetate. Claims of Zr(O2CCH3)4 [1] have been superseded by experiments using X-ray crystallography. [2]
The species Zr6O4(OH)4(O2CCH3)12 is a common precursor to metal-organic frameworks (MOFs). [3]
https://doi.org/10.1021/acs.inorgchem.6b01624 Copyright © 2017 American Chemical Society RIGHTS & PERMISSIONS Subscribed Access Article Views 3592 Altmetric 5 Citations 57 LEARN ABOUT THESE METRICS Share
Add to
Export
RIS PDF (2 MB) OpenURL UNIV ILLINOIS URBANA-CHAMPAIGNSupporting Info (2)»Supporting Information SUBJECTS:Cluster chemistry, Go to Inorganic Chemistry Inorganic Chemistry Abstract
Complex formation and the coordination of zirconium with acetic acid were investigated with Zr K-edge extended X-ray absorption fine structure spectroscopy (EXAFS) and single-crystal diffraction. Zr K-edge EXAFS spectra show that a stepwise increase of acetic acid in aqueous solution with 0.1 M Zr(IV) leads to a structural rearrangement from initial tetranuclear hydrolysis species [Zr4(OH)8(OH2)16]8+ to a hexanuclear acetate species Zr6(O)4(OH)4(CH3COO)12.