This article needs additional citations for
verification. (January 2021) |
X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]
XAS data is obtained by tuning the photon energy, [3] using a crystalline monochromator, to a range where core electrons can be excited (0.1-100 keV). The edges are, in part, named by which core electron is excited: the principal quantum numbers n = 1, 2, and 3, correspond to the K-, L-, and M-edges, respectively. [4] For instance, excitation of a 1s electron occurs at the K-edge, while excitation of a 2s or 2p electron occurs at an L-edge (Figure 1).
There are three main regions found on a spectrum generated by XAS data which are then thought of as separate spectroscopic techniques (Figure 2):
XAS is a type of absorption spectroscopy from a core initial state with a well defined symmetry; therefore, the quantum mechanical selection rules select the symmetry of the final states in the continuum, which are usually a mixture of multiple components. The most intense features are due to electric-dipole allowed transitions (i.e. Δℓ = ± 1) to unoccupied final states. For example, the most intense features of a K-edge are due to core transitions from 1s → p-like final states, while the most intense features of the L3-edge are due to 2p → d-like final states.
XAS methodology can be broadly divided into four experimental categories that can give complementary results to each other: metal K-edge, metal L-edge, ligand K-edge, and EXAFS.
The most obvious means of mapping heterogeneous samples beyond x‐ray absorption contrast is through elemental analysis by x‐ray fluorescence, akin to EDX methods in electron microscopy. [5]
XAS is a technique used in different scientific fields including molecular and condensed matter physics, [6] [7] [8] materials science and engineering, chemistry, earth science, and biology. In particular, its unique sensitivity to the local structure, as compared to x-ray diffraction, have been exploited for studying:
{{
cite book}}
: CS1 maint: location missing publisher (
link)
This article needs additional citations for
verification. (January 2021) |
X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]
XAS data is obtained by tuning the photon energy, [3] using a crystalline monochromator, to a range where core electrons can be excited (0.1-100 keV). The edges are, in part, named by which core electron is excited: the principal quantum numbers n = 1, 2, and 3, correspond to the K-, L-, and M-edges, respectively. [4] For instance, excitation of a 1s electron occurs at the K-edge, while excitation of a 2s or 2p electron occurs at an L-edge (Figure 1).
There are three main regions found on a spectrum generated by XAS data which are then thought of as separate spectroscopic techniques (Figure 2):
XAS is a type of absorption spectroscopy from a core initial state with a well defined symmetry; therefore, the quantum mechanical selection rules select the symmetry of the final states in the continuum, which are usually a mixture of multiple components. The most intense features are due to electric-dipole allowed transitions (i.e. Δℓ = ± 1) to unoccupied final states. For example, the most intense features of a K-edge are due to core transitions from 1s → p-like final states, while the most intense features of the L3-edge are due to 2p → d-like final states.
XAS methodology can be broadly divided into four experimental categories that can give complementary results to each other: metal K-edge, metal L-edge, ligand K-edge, and EXAFS.
The most obvious means of mapping heterogeneous samples beyond x‐ray absorption contrast is through elemental analysis by x‐ray fluorescence, akin to EDX methods in electron microscopy. [5]
XAS is a technique used in different scientific fields including molecular and condensed matter physics, [6] [7] [8] materials science and engineering, chemistry, earth science, and biology. In particular, its unique sensitivity to the local structure, as compared to x-ray diffraction, have been exploited for studying:
{{
cite book}}
: CS1 maint: location missing publisher (
link)