Xerosydryle is a new class of materials, solid at ambient pressure and temperature, deriving from the supramolecular organization of liquid water. The fundamental molecular constituent of xerosydryle is water (H2O), and it is found in liquid water, mixed with it. It has been observed aggregated in small volumes (domains), and it can be separated from liquid water and accumulated in clumps, with the appropriate techniques. The accumulated clumps of xerosydryle appear as a white-ish fluffy, dry substance, stable over time and at high temperature: it can be heated up to 950°C and preserve 10 - 30% of the initial mass. The clumps of dry xerosydryle, once separated, are easily soluble back in water [1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11].
As early as late 1960s and early 1970s, the researcher Drost-Hansen reported the first observations of a different behavior of water molecules close to the walls of its container later called exclusion zone, collecting findings of many earlier experiments [12] [13]. In 1986 Deryagin and his colleagues observed an exclusion zone next to the walls of biological cells [14].
In 2006 the group of Gerald Pollack reported their observations, and used for the first time the term exclusion zone. They observed that the particles of colloidal and molecular solutes suspended in aqueous solution are excluded from a layer of volume next to hydrophilic surfaces [15]. The exclusion zone has been observed and characterized by several independent groups since those early observations [16] [17] [18].
Starting from 2013 the research group of Vittorio Elia and Roberto Germano, following the path of their preceding research, and in collaboration with other international researchers, reproduced also the observations of the exclusion zone done by Gerald Pollack, and extended that research, developing a protocol to separate and collect a dry residual from pure water, after putting it in contact with different hydrophilic materials (see preparation techniques). They have advanced the hypothesis that the clumps of white solid material that they can extract from pure water consists of clumps of the same supramolecular structures of pure water that constitute the exclusion zone [8] [10]. They have named this class of materials Xerosydryle [19].
The generation of these sovramolecular H2O nanoclusters that are solid at ambient pressure and temperature is faced by Roberto Germano [20] in the frame of the QED applied to the solid state physics, starting from the structure of the liquid water as derived by the quantum electrodynamical calculations shown by Emilio Del Giudice and his colleagues in 2013 [21].
In these calculations comes out that liquid bulk water has a two phase structure: one phase is in a gas-similar state with molecules that have weak bonds between them. The other phase is composed by small volumes in the bulk (called coherence domains) where the water molecules are in a different state, oscillating in phase among two energetic levels. This state (coherent state ) should be described by quantum mechanics and quantum electrodynamics. The cloud of electrons of the water molecules superstructure oscillate between two quantum states: (a) a ground state, and (b) an excited state. In the excited state one electron per molecule has an higher energy and is almost free (with a binding energy of about 0.5 eV). This coherent state is a quantum superposition of the two states (a) and (b), and the quantum superposition has a component with coefficient 0.9 of the ground state, and a component with 0.1 of the excited state. The electrons in this quantum state oscillate between the ground state and the excited state with a certain frequency, and this oscillation creates an electromagnetic field, which is confined within the super-molecular structure, so that no radiation is observed. [21] [19].
Here is the procedure to obtain the solid and dry xerosydryle. The start is ultrapure water. Then, a piece of hydrophilic material is immersed in the water. The material can be e.g. hydrophilic cotton, cellophane, Nafion. The water and the hydrophilic material are kept in a container for 15 or 30 minutes. The water is then squeezed away from the material, and released back in the container, with hands, wearing polyethylene gloves. The specimen of hydrophilic material is dried at room conditions, and a small sample of water is taken from the container, for measurements. After around 12 hours the cycle is repeated, immersing the sample in the water container, letting interact, and removing. The cycles are repeated for several tens of times [8] [10].
Finally, to remove the liquid water, a process of lyophilization is applied, i.e. a cycle of freezing below the triple point and then drying by sublimation. After the lyophilization, a solid residue is collected. This solid residue can be as much as few grams per 1 liter of initial pure water, equivalent to some kg for m3 of initial pure water [11].
In all the experimental procedures, a great effort is taken in avoiding to contaminate the water. Moreover, many measurements are performed, and some arguments are presented, to exclude that the solid xerosydryle material extracted is somehow due to the impurities still present in the water sample.
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Xerosydryle is a new class of materials, solid at ambient pressure and temperature, deriving from the supramolecular organization of liquid water. The fundamental molecular constituent of xerosydryle is water (H2O), and it is found in liquid water, mixed with it. It has been observed aggregated in small volumes (domains), and it can be separated from liquid water and accumulated in clumps, with the appropriate techniques. The accumulated clumps of xerosydryle appear as a white-ish fluffy, dry substance, stable over time and at high temperature: it can be heated up to 950°C and preserve 10 - 30% of the initial mass. The clumps of dry xerosydryle, once separated, are easily soluble back in water [1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11].
As early as late 1960s and early 1970s, the researcher Drost-Hansen reported the first observations of a different behavior of water molecules close to the walls of its container later called exclusion zone, collecting findings of many earlier experiments [12] [13]. In 1986 Deryagin and his colleagues observed an exclusion zone next to the walls of biological cells [14].
In 2006 the group of Gerald Pollack reported their observations, and used for the first time the term exclusion zone. They observed that the particles of colloidal and molecular solutes suspended in aqueous solution are excluded from a layer of volume next to hydrophilic surfaces [15]. The exclusion zone has been observed and characterized by several independent groups since those early observations [16] [17] [18].
Starting from 2013 the research group of Vittorio Elia and Roberto Germano, following the path of their preceding research, and in collaboration with other international researchers, reproduced also the observations of the exclusion zone done by Gerald Pollack, and extended that research, developing a protocol to separate and collect a dry residual from pure water, after putting it in contact with different hydrophilic materials (see preparation techniques). They have advanced the hypothesis that the clumps of white solid material that they can extract from pure water consists of clumps of the same supramolecular structures of pure water that constitute the exclusion zone [8] [10]. They have named this class of materials Xerosydryle [19].
The generation of these sovramolecular H2O nanoclusters that are solid at ambient pressure and temperature is faced by Roberto Germano [20] in the frame of the QED applied to the solid state physics, starting from the structure of the liquid water as derived by the quantum electrodynamical calculations shown by Emilio Del Giudice and his colleagues in 2013 [21].
In these calculations comes out that liquid bulk water has a two phase structure: one phase is in a gas-similar state with molecules that have weak bonds between them. The other phase is composed by small volumes in the bulk (called coherence domains) where the water molecules are in a different state, oscillating in phase among two energetic levels. This state (coherent state ) should be described by quantum mechanics and quantum electrodynamics. The cloud of electrons of the water molecules superstructure oscillate between two quantum states: (a) a ground state, and (b) an excited state. In the excited state one electron per molecule has an higher energy and is almost free (with a binding energy of about 0.5 eV). This coherent state is a quantum superposition of the two states (a) and (b), and the quantum superposition has a component with coefficient 0.9 of the ground state, and a component with 0.1 of the excited state. The electrons in this quantum state oscillate between the ground state and the excited state with a certain frequency, and this oscillation creates an electromagnetic field, which is confined within the super-molecular structure, so that no radiation is observed. [21] [19].
Here is the procedure to obtain the solid and dry xerosydryle. The start is ultrapure water. Then, a piece of hydrophilic material is immersed in the water. The material can be e.g. hydrophilic cotton, cellophane, Nafion. The water and the hydrophilic material are kept in a container for 15 or 30 minutes. The water is then squeezed away from the material, and released back in the container, with hands, wearing polyethylene gloves. The specimen of hydrophilic material is dried at room conditions, and a small sample of water is taken from the container, for measurements. After around 12 hours the cycle is repeated, immersing the sample in the water container, letting interact, and removing. The cycles are repeated for several tens of times [8] [10].
Finally, to remove the liquid water, a process of lyophilization is applied, i.e. a cycle of freezing below the triple point and then drying by sublimation. After the lyophilization, a solid residue is collected. This solid residue can be as much as few grams per 1 liter of initial pure water, equivalent to some kg for m3 of initial pure water [11].
In all the experimental procedures, a great effort is taken in avoiding to contaminate the water. Moreover, many measurements are performed, and some arguments are presented, to exclude that the solid xerosydryle material extracted is somehow due to the impurities still present in the water sample.
{{
cite journal}}
: CS1 maint: extra punctuation (
link)
{{
cite journal}}
: CS1 maint: extra punctuation (
link)
{{
cite journal}}
: CS1 maint: extra punctuation (
link)
{{
cite journal}}
: CS1 maint: unflagged free DOI (
link)