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The majority of the text here appears to be copied directly from the source listed in the article. Is this kosher? Man It's So Loud In Here ( talk) 23:31, 6 December 2007 (UTC)
Tell me if I say bullshit, but isn't it that in the definition of the transition dipole moment, Ψ represents only the electronic spatial coordinate part and not the full wavefunction of the system? (I mean, not the nuclear/vibrational function, nor the spin function)... if yes, maybe it should be said explicitly... -- Der.Gogo ( talk) 15:36, 14 September 2011 (UTC)
Is it OK that in 1st definition d is given as a vector quantity whereas d_mn defines an element of matrix d? No, it is not OK. d operator must be defined as a one proportional to Pauli matrices d ~ (sx,sy,sz) so that it forms a vector with operators inside (a tensor operator). Consider how confusing the current definition is, if to attempt a construction of -d.E. For this case both must be operators (matrix form). If d is defined as a vector, then E must also be defined as a vector, but then d_mn is meaningless, because it defines d as a matrix, not a vector. Tormondo ( talk) 14:48, 30 December 2011 (UTC)
![]() | This article is rated Start-class on Wikipedia's
content assessment scale. It is of interest to the following WikiProjects: | ||||||||||
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The majority of the text here appears to be copied directly from the source listed in the article. Is this kosher? Man It's So Loud In Here ( talk) 23:31, 6 December 2007 (UTC)
Tell me if I say bullshit, but isn't it that in the definition of the transition dipole moment, Ψ represents only the electronic spatial coordinate part and not the full wavefunction of the system? (I mean, not the nuclear/vibrational function, nor the spin function)... if yes, maybe it should be said explicitly... -- Der.Gogo ( talk) 15:36, 14 September 2011 (UTC)
Is it OK that in 1st definition d is given as a vector quantity whereas d_mn defines an element of matrix d? No, it is not OK. d operator must be defined as a one proportional to Pauli matrices d ~ (sx,sy,sz) so that it forms a vector with operators inside (a tensor operator). Consider how confusing the current definition is, if to attempt a construction of -d.E. For this case both must be operators (matrix form). If d is defined as a vector, then E must also be defined as a vector, but then d_mn is meaningless, because it defines d as a matrix, not a vector. Tormondo ( talk) 14:48, 30 December 2011 (UTC)