A protocrystalline phase is a distinct phase occurring during crystal growth, which evolves into a microcrystalline form. The term is typically associated with silicon films in optical applications such as solar cells. [1]
Amorphous silicon (a-Si) is a popular solar cell material owing to its low cost and ease of production. Owing to its disordered structure ( Urbach tail), its absorption extends to the energies below the band gap, resulting in a wide-range spectral response; however, it has a relatively low solar cell efficiency. Protocrystalline Si (pc-Si:H) also has a relatively low absorption near the band gap, owing to its more ordered crystalline structure. Thus, protocrystalline and amorphous silicon can be combined in a tandem solar cell, where the top thin layer of a-Si:H absorbs short-wavelength light whereas the underlying protocrystalline silicon layer absorbs the longer wavelengths [2]
A protocrystalline phase is a distinct phase occurring during crystal growth, which evolves into a microcrystalline form. The term is typically associated with silicon films in optical applications such as solar cells. [1]
Amorphous silicon (a-Si) is a popular solar cell material owing to its low cost and ease of production. Owing to its disordered structure ( Urbach tail), its absorption extends to the energies below the band gap, resulting in a wide-range spectral response; however, it has a relatively low solar cell efficiency. Protocrystalline Si (pc-Si:H) also has a relatively low absorption near the band gap, owing to its more ordered crystalline structure. Thus, protocrystalline and amorphous silicon can be combined in a tandem solar cell, where the top thin layer of a-Si:H absorbs short-wavelength light whereas the underlying protocrystalline silicon layer absorbs the longer wavelengths [2]