FFKMs (by ASTM 1418 standard) (equivalent to FFPMs by ISO/DIN 1629 standard) are perfluoroelastomeric compounds containing an even higher amount of fluorine than FKM fluoroelastomers.

They have improved resistance to high temperatures ^{[1] [2]} and chemicals and even withstand environments where Oxygen-Plasma are present for many hours. Certain grades have a maximum continuous service temperature of 327 °C (621 °F). They are commonly used to make O-rings and gaskets that are used in applications that involve contact with hydrocarbons or highly corrosive fluids, or when a wide range of temperatures is encountered.

For vacuum applications, demanding very low contamination (out-gassing and particle emission) as well as high temperature operation (200–300 °C) for prolonged out-baking or processing times and where a copper or metal sealing is not possible or very inconvenient/expensive, a custom-made, clean-room manufactured, sealing such as Kalrez® 9100, ^[3] SCVBR, ^[4] Chemraz®, ^[5] or Perlast ^[6] can be used. After manufacturing, they are O-plasma vacuum cleaned (and/or vacuum baked) to reach out-gassing performance similar to Teflon while reaching vacuum leak tightness ( permeability rates) similar to FKM ( Viton) compounds. This combination of properties allows FFKM seals to reach well into UHV pressures without the use of metal sealing. However, they are significantly more expensive than standard FKM O-rings.

References