Paratooite-(La) | |
---|---|
General | |
Category | Carbonate mineral |
Formula (repeating unit) | (La,Sr,Ca)4CuCa(Na,Ca)2(CO3)8 |
IMA symbol | Pto-La [1] |
Strunz classification | 5/B.0; 5.AD.20 (Nickel-Strunz) |
Crystal system | Orthorhombic |
Crystal class | Dipyramidal: mmm |
Space group | Pbam |
Unit cell | a = 7.2250, b = 12.7626 c = 10.0559 [Å] |
Identification | |
Color | pale turquoise-blue to pale blue |
Crystal habit | blades (sheaves) intergrown to form spray-like aggregates |
Cleavage | {100} (possible) |
Mohs scale hardness | 4 (probably) |
Luster | vitreous or pearly |
Streak | pale blue |
Specific gravity | 1.97-2.02 (measured) |
Optical properties | biaxial negative, α = 1.605(3), β = 1.696(3), γ = 1.752(2) |
Pleochroism | moderate, very pale blue (X) to greenish blue (Y = Z) |
2V angle | 72.6 ° |
References | [2] [3] [4] |
Paratooite-(La) is a complex lanthanum copper(II) calcium sodium carbonate mineral, representing a unique elemental combination among the known minerals. It is a secondary, weathering mineral. [5] [6] [7] There is a heterovalent diadochy substitution of lanthanum by strontium and calcium; also sodium is substituted by calcium in the mineral. Its structure proved to be more difficult to describe within the initial approach. It was later shown to be a superstructure of another rare earth carbonate mineral, carbocernaite. [8] The "-(La)" suffix in the mineral's name is known as Levinson suffix. It refers to the particular element, of a group of elements (notably lanthanides), that dominates in the particular structural site. As such, the element would show major, dominant occupancy at this particular site. [9]
Paratooite-(La) | |
---|---|
General | |
Category | Carbonate mineral |
Formula (repeating unit) | (La,Sr,Ca)4CuCa(Na,Ca)2(CO3)8 |
IMA symbol | Pto-La [1] |
Strunz classification | 5/B.0; 5.AD.20 (Nickel-Strunz) |
Crystal system | Orthorhombic |
Crystal class | Dipyramidal: mmm |
Space group | Pbam |
Unit cell | a = 7.2250, b = 12.7626 c = 10.0559 [Å] |
Identification | |
Color | pale turquoise-blue to pale blue |
Crystal habit | blades (sheaves) intergrown to form spray-like aggregates |
Cleavage | {100} (possible) |
Mohs scale hardness | 4 (probably) |
Luster | vitreous or pearly |
Streak | pale blue |
Specific gravity | 1.97-2.02 (measured) |
Optical properties | biaxial negative, α = 1.605(3), β = 1.696(3), γ = 1.752(2) |
Pleochroism | moderate, very pale blue (X) to greenish blue (Y = Z) |
2V angle | 72.6 ° |
References | [2] [3] [4] |
Paratooite-(La) is a complex lanthanum copper(II) calcium sodium carbonate mineral, representing a unique elemental combination among the known minerals. It is a secondary, weathering mineral. [5] [6] [7] There is a heterovalent diadochy substitution of lanthanum by strontium and calcium; also sodium is substituted by calcium in the mineral. Its structure proved to be more difficult to describe within the initial approach. It was later shown to be a superstructure of another rare earth carbonate mineral, carbocernaite. [8] The "-(La)" suffix in the mineral's name is known as Levinson suffix. It refers to the particular element, of a group of elements (notably lanthanides), that dominates in the particular structural site. As such, the element would show major, dominant occupancy at this particular site. [9]