Names | |
---|---|
Preferred IUPAC name
Magnesium bis(2-carbonoperoxoylbenzoate) | |
Other names
H48; MMPP
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
ECHA InfoCard | 100.071.808 |
EC Number |
|
PubChem
CID
|
|
UNII | |
CompTox Dashboard (
EPA)
|
|
| |
Properties | |
C16H10MgO10 | |
Molar mass | 386.551 g·mol−1 |
Hazards | |
Flash point | 173.4 °C (344.1 °F; 446.5 K) |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Magnesium monoperoxyphthalate (MMPP) is a water-soluble peroxy acid used as an oxidant in organic synthesis. Its main areas of use are the conversion of ketones to esters ( Baeyer-Villiger oxidation), epoxidation of alkenes ( Prilezhaev reaction), oxidation of sulfides to sulfoxides and sulfones, oxidation of amines to produce amine oxides, and in the oxidative cleavage of hydrazones. [1]
Due to its insolubility in non-polar solvents MMPP has seen less use than the more widely used meta-chloroperoxybenzoic acid (mCPBA). Although work up procedures are more simply handled in polar solvents, usage of MMPP to oxidize nonpolar substrates in biphasic media combined with a phase transfer catalyst have been inefficient. [1] Despite this MMPP has certain advantages over mCPBA including a lower cost of production and increased stability. [1]
MMPP is also used as the active ingredient in certain surface disinfectants such as Dismozon Pur. [2] As a surface disinfectant MMPP exhibits a broad spectrum biocidal effect including inactivation of endospores. [3] Its wide surface compatibility enables its use on sensitive materials, such as plastic and rubber equipment used in hospitals. Additionally MMPP has been investigated as a potential antibacterial agent for mouthwashes and toothpaste. [4]
Names | |
---|---|
Preferred IUPAC name
Magnesium bis(2-carbonoperoxoylbenzoate) | |
Other names
H48; MMPP
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
ECHA InfoCard | 100.071.808 |
EC Number |
|
PubChem
CID
|
|
UNII | |
CompTox Dashboard (
EPA)
|
|
| |
Properties | |
C16H10MgO10 | |
Molar mass | 386.551 g·mol−1 |
Hazards | |
Flash point | 173.4 °C (344.1 °F; 446.5 K) |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Magnesium monoperoxyphthalate (MMPP) is a water-soluble peroxy acid used as an oxidant in organic synthesis. Its main areas of use are the conversion of ketones to esters ( Baeyer-Villiger oxidation), epoxidation of alkenes ( Prilezhaev reaction), oxidation of sulfides to sulfoxides and sulfones, oxidation of amines to produce amine oxides, and in the oxidative cleavage of hydrazones. [1]
Due to its insolubility in non-polar solvents MMPP has seen less use than the more widely used meta-chloroperoxybenzoic acid (mCPBA). Although work up procedures are more simply handled in polar solvents, usage of MMPP to oxidize nonpolar substrates in biphasic media combined with a phase transfer catalyst have been inefficient. [1] Despite this MMPP has certain advantages over mCPBA including a lower cost of production and increased stability. [1]
MMPP is also used as the active ingredient in certain surface disinfectants such as Dismozon Pur. [2] As a surface disinfectant MMPP exhibits a broad spectrum biocidal effect including inactivation of endospores. [3] Its wide surface compatibility enables its use on sensitive materials, such as plastic and rubber equipment used in hospitals. Additionally MMPP has been investigated as a potential antibacterial agent for mouthwashes and toothpaste. [4]