From Wikipedia, the free encyclopedia

This page provides supplementary chemical data on Lithium chloride.

Solubility

Solubility of LiCl in various solvents
(g LiCl / 100g of solvent at 25 °C)
H2O 84.5
Liquid ammonia 3.02
Liquid sulfur dioxide 0.012
Methanol 21 - 41
Formic acid 27.5
Sulfolane 1.5
Acetonitrile 0.14
Acetone 0.83
Formamide 28.2
Dimethylformamide 11 - 28
Reference:
Burgess, J. Metal Ions in Solution
(Ellis Horwood, New York, 1978)
ISBN  0-85312-027-7

Thermodynamic properties

Phase behavior
Triple point ? K (? °C), ? Pa
Critical point ? K (? °C), ? Pa
Std enthalpy
of fusion
ΔfusHo
+19.9 kJ/mol
Std entropy
of fusion
ΔfusSo
? J/(mol·K)
Std enthalpy
of vaporization
ΔvapHo
? kJ/mol
Std entropy
of vaporization
ΔvapSo
? J/(mol·K)
Solid properties
Std enthalpy
of formation
ΔfHosolid
−408.27 kJ/mol
Standard molar entropy
Sosolid
59.33 J/(mol K)
Heat capacity cp 47.99 J/(mol K)
Liquid properties
Std enthalpy
of formation
ΔfHoliquid
−390.76 kJ/mol
Standard molar entropy
Soliquid
? J/(mol K)
Heat capacity cp ? J/(mol K)
Gas properties
Std enthalpy
of formation
ΔfHogas
−195.2 kJ/mol
Standard molar entropy
Sogas
212.7 J/(mol K)
Heat capacity cp 33.2 J/(mol K)

Spectral data

UV-Vis
Lambda-max ? nm
Extinction coefficient ?
IR
Major absorption bands ? cm−1
NMR
Proton NMR
Carbon-13 NMR
Other NMR data
MS
Masses of
main fragments

Structure and properties data

Structure and properties
Index of refraction 1.662
Dielectric constant ? C2/(N·m2) at ? °C
Bond strength ?
Bond length ?
Magnetic susceptibility -24.3 cgs units

Temperature Relative Humidity over saturated solution in water [1]

Temperature(C) Relative Humidity(%)
0.23 14.7
9.56 13.4
19.22 12.4
29.64 11.8
39.64 11.8
46.76 11.4

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ( MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

  This box:   

References

  • Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD)
From Wikipedia, the free encyclopedia

This page provides supplementary chemical data on Lithium chloride.

Solubility

Solubility of LiCl in various solvents
(g LiCl / 100g of solvent at 25 °C)
H2O 84.5
Liquid ammonia 3.02
Liquid sulfur dioxide 0.012
Methanol 21 - 41
Formic acid 27.5
Sulfolane 1.5
Acetonitrile 0.14
Acetone 0.83
Formamide 28.2
Dimethylformamide 11 - 28
Reference:
Burgess, J. Metal Ions in Solution
(Ellis Horwood, New York, 1978)
ISBN  0-85312-027-7

Thermodynamic properties

Phase behavior
Triple point ? K (? °C), ? Pa
Critical point ? K (? °C), ? Pa
Std enthalpy
of fusion
ΔfusHo
+19.9 kJ/mol
Std entropy
of fusion
ΔfusSo
? J/(mol·K)
Std enthalpy
of vaporization
ΔvapHo
? kJ/mol
Std entropy
of vaporization
ΔvapSo
? J/(mol·K)
Solid properties
Std enthalpy
of formation
ΔfHosolid
−408.27 kJ/mol
Standard molar entropy
Sosolid
59.33 J/(mol K)
Heat capacity cp 47.99 J/(mol K)
Liquid properties
Std enthalpy
of formation
ΔfHoliquid
−390.76 kJ/mol
Standard molar entropy
Soliquid
? J/(mol K)
Heat capacity cp ? J/(mol K)
Gas properties
Std enthalpy
of formation
ΔfHogas
−195.2 kJ/mol
Standard molar entropy
Sogas
212.7 J/(mol K)
Heat capacity cp 33.2 J/(mol K)

Spectral data

UV-Vis
Lambda-max ? nm
Extinction coefficient ?
IR
Major absorption bands ? cm−1
NMR
Proton NMR
Carbon-13 NMR
Other NMR data
MS
Masses of
main fragments

Structure and properties data

Structure and properties
Index of refraction 1.662
Dielectric constant ? C2/(N·m2) at ? °C
Bond strength ?
Bond length ?
Magnetic susceptibility -24.3 cgs units

Temperature Relative Humidity over saturated solution in water [1]

Temperature(C) Relative Humidity(%)
0.23 14.7
9.56 13.4
19.22 12.4
29.64 11.8
39.64 11.8
46.76 11.4

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ( MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

  This box:   

References

  • Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD)

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