From Wikipedia, the free encyclopedia
Iron tetraboride
Names
IUPAC name
Iron tetraboride
Identifiers
InChI=1S/4B.Fe
Key: JRZHEZVJDLIZIR-UHFFFAOYSA-N
Properties
FeB4
Molar mass
99.0920 g/mol
Structure
orthorhombic
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Iron tetraboride (FeB4 ) is a
superhard
superconductor (
Tc < 3
K ) consisting of
iron and
boron . Iron tetraboride does not occur in nature and can be created synthetically.
[1]
[2] Its molecular structure was predicted using computer models.
[3]
See also
References
^ Gou, Huiyang (18 April 2013). "Discovery of a superhard iron tetraboride superconductor". Physical Review Letters . 111 (15): 157002.
arXiv :
1304.5106 .
Bibcode :
2013PhRvL.111o7002G .
doi :
10.1103/PhysRevLett.111.157002 .
PMID
24160619 .
S2CID
11906548 .
^ Gou, Huiyang; Dubrovinskaia, Natalia; Bykova, Elena; Tsirlin, Alexander A.; Kasinathan, Deepa; Schnelle, Walter; Richter, Asta; Merlini, Marco; Hanfland, Michael; Abakumov, Artem M.; Batuk, Dmitry; Van Tendeloo, Gustaaf; Nakajima, Yoichi; Kolmogorov, Aleksey N.; Dubrovinsky, Leonid (11 October 2013).
"Discovery of a Superhard Iron Tetraboride Superconductor" . Physical Review Letters . 111 (157002): 157002.
arXiv :
1304.5106 .
Bibcode :
2013PhRvL.111o7002G .
doi :
10.1103/PhysRevLett.111.157002 .
PMID
24160619 .
S2CID
11906548 . Retrieved 17 October 2013 .
^ Rachel Coker (8 October 2013).
"First Computer-Designed Superconductor Created" . ScienceDaily . Retrieved 25 November 2013 .
Zhang, Xinyu; Qin, Jiaqian; Xue, Yanan; Zhang, Shiliang; Jing, Qin; Ma, Mingzhen; Liu, Riping (2013). "Deformation-induced bonding evolution of iron tetraboride and its electronic origin".
Physica Status Solidi RRL . 7 (11): 1022.
Bibcode :
2013PSSRR...7.1022Z .
doi :
10.1002/pssr.201308086 .
S2CID
94273648 .
Zhang, Xinyu; Qin, Jiaqian; Ning, Jinliang; Sun, Xiaowei; Li, Xinting; Ma, Mingzhen; Liu, Riping (2013). "First principle study of elastic and thermodynamic properties of FeB4 under high pressure".
Journal of Applied Physics . 114 (18): 183517–183517–7.
Bibcode :
2013JAP...114r3517Z .
doi :
10.1063/1.4829926 .
External links
Fe(-II) Fe(0) Fe(I)
Fe(0,II) Fe(II)
Fe(0,III) Fe(II,III) Fe(III) Organoiron(III) compounds
Fe(IV) Fe(VI) Purported