From Wikipedia, the free encyclopedia
Ethyl hydroperoxide
Names
IUPAC name
Ethaneperoxol
Other names
Hydroperoxide, ethyl
Ethane hydroperoxide
Ethyl hydrogen peroxide
Hydroperoxyethane
Identifiers
3D model ( JSmol)
ChemSpider
ECHA InfoCard 100.019.284 Edit this at Wikidata
EC Number
  • 221-211-6
PubChem CID
UNII
  • InChI=1S/C2H6O2/c1-2-4-3/h3H,2H2,1H3
    Key: ILHIHKRJJMKBEE-UHFFFAOYSA-N
  • CCOO
Properties
C2H6O2
Molar mass 62.068 g·mol−1
Appearance colorless liquid
Melting point −100 °C (−148 °F; 173 K)
Boiling point 95 °C (203 °F; 368 K)
Miscible in water and diethyl ether
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ethyl hydroperoxide is the organic compound with the formula CH3CH2OOH. It is a colorless liquid that is miscible with water and diethyl ether.

Formation

Ethyl hydroperoxide is formed in the flame of burning alkanes. [1] Ethyl hydroperoxide is also formed in the catalytic reaction of ethane and hydrogen peroxide. [2] Yet another way to form ethyl hydroperoxide is by a photocatalytic oxidation of ethane: [3]

CH3CH3 + O2 → CH3CH2OOH

References

  1. ^ Bierkandt, Thomas; Oßwald, Patrick; Gaiser, Nina; Krüger, Dominik; Köhler, Markus; Hoener, Martin; Shaqiri, Shkelqim; Kaczmarek, Dennis; Karakaya, Yasin; Hemberger, Patrick; Kasper, Tina (October 2021). "Observation of low‐temperature chemistry products in laminar premixed low‐pressure flames by molecular‐beam mass spectrometry". International Journal of Chemical Kinetics. 53 (10): 1063–1081. doi: 10.1002/kin.21503. S2CID  236545874.
  2. ^ Forde, Michael M.; Armstrong, Robert D.; Hammond, Ceri; He, Qian; Jenkins, Robert L.; Kondrat, Simon A.; Dimitratos, Nikolaos; Lopez-Sanchez, Jose Antonio; Taylor, Stuart H.; Willock, David; Kiely, Christopher J.; Hutchings, Graham John (31 July 2013). "Partial Oxidation of Ethane to Oxygenates Using Fe- and Cu-Containing ZSM-5". Journal of the American Chemical Society. 135 (30): 11087–11099. doi: 10.1021/ja403060n. PMID  23802759.
  3. ^ Zhu, Yao; Fang, Siyuan; Chen, Shaoqin; Tong, Youjie; Wang, Chunling; Hu, Yun Hang (2021). "Highly efficient visible-light photocatalytic ethane oxidation into ethyl hydroperoxide as a radical reservoir". Chemical Science. 12 (16): 5825–5833. doi: 10.1039/D1SC00694K. PMC  8179680. PMID  34168807.
From Wikipedia, the free encyclopedia
Ethyl hydroperoxide
Names
IUPAC name
Ethaneperoxol
Other names
Hydroperoxide, ethyl
Ethane hydroperoxide
Ethyl hydrogen peroxide
Hydroperoxyethane
Identifiers
3D model ( JSmol)
ChemSpider
ECHA InfoCard 100.019.284 Edit this at Wikidata
EC Number
  • 221-211-6
PubChem CID
UNII
  • InChI=1S/C2H6O2/c1-2-4-3/h3H,2H2,1H3
    Key: ILHIHKRJJMKBEE-UHFFFAOYSA-N
  • CCOO
Properties
C2H6O2
Molar mass 62.068 g·mol−1
Appearance colorless liquid
Melting point −100 °C (−148 °F; 173 K)
Boiling point 95 °C (203 °F; 368 K)
Miscible in water and diethyl ether
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ethyl hydroperoxide is the organic compound with the formula CH3CH2OOH. It is a colorless liquid that is miscible with water and diethyl ether.

Formation

Ethyl hydroperoxide is formed in the flame of burning alkanes. [1] Ethyl hydroperoxide is also formed in the catalytic reaction of ethane and hydrogen peroxide. [2] Yet another way to form ethyl hydroperoxide is by a photocatalytic oxidation of ethane: [3]

CH3CH3 + O2 → CH3CH2OOH

References

  1. ^ Bierkandt, Thomas; Oßwald, Patrick; Gaiser, Nina; Krüger, Dominik; Köhler, Markus; Hoener, Martin; Shaqiri, Shkelqim; Kaczmarek, Dennis; Karakaya, Yasin; Hemberger, Patrick; Kasper, Tina (October 2021). "Observation of low‐temperature chemistry products in laminar premixed low‐pressure flames by molecular‐beam mass spectrometry". International Journal of Chemical Kinetics. 53 (10): 1063–1081. doi: 10.1002/kin.21503. S2CID  236545874.
  2. ^ Forde, Michael M.; Armstrong, Robert D.; Hammond, Ceri; He, Qian; Jenkins, Robert L.; Kondrat, Simon A.; Dimitratos, Nikolaos; Lopez-Sanchez, Jose Antonio; Taylor, Stuart H.; Willock, David; Kiely, Christopher J.; Hutchings, Graham John (31 July 2013). "Partial Oxidation of Ethane to Oxygenates Using Fe- and Cu-Containing ZSM-5". Journal of the American Chemical Society. 135 (30): 11087–11099. doi: 10.1021/ja403060n. PMID  23802759.
  3. ^ Zhu, Yao; Fang, Siyuan; Chen, Shaoqin; Tong, Youjie; Wang, Chunling; Hu, Yun Hang (2021). "Highly efficient visible-light photocatalytic ethane oxidation into ethyl hydroperoxide as a radical reservoir". Chemical Science. 12 (16): 5825–5833. doi: 10.1039/D1SC00694K. PMC  8179680. PMID  34168807.

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