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Names | |
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IUPAC name
Ruthenium(II,III) acetate chloride
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Other names
Tetrakis(mu-(acetato-O:O'))chlorodiruthenium
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Identifiers | |
3D model (
JSmol)
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ChemSpider | |
EC Number |
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PubChem
CID
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Properties | |
C8H12ClO8Ru2 | |
Molar mass | 473.77 g·mol−1 |
Appearance | red-brown solid |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
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Diruthenium tetraacetate chloride is the coordination polymer with the formula {[Ru2(O2CCH3)4]Cl}n. A red brown solid, the compound is obtained by the reduction of ruthenium trichloride in acetic acid. [1] The compound has attracted much academic interest because it features a fractional metal-metal bond order of 2.5. [2]
The [Ru2(O2CCH3)4+ core adopts the Chinese lantern structure, with four acetate ligands spanning the Ru2 center. The Ru-Ru distance is 228 pm. [3] [4] The [Ru2(O2CCH3)4+ units are linked by bridging chloride ligands.
![]() | |
Names | |
---|---|
IUPAC name
Ruthenium(II,III) acetate chloride
| |
Other names
Tetrakis(mu-(acetato-O:O'))chlorodiruthenium
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
EC Number |
|
PubChem
CID
|
|
| |
| |
Properties | |
C8H12ClO8Ru2 | |
Molar mass | 473.77 g·mol−1 |
Appearance | red-brown solid |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Diruthenium tetraacetate chloride is the coordination polymer with the formula {[Ru2(O2CCH3)4]Cl}n. A red brown solid, the compound is obtained by the reduction of ruthenium trichloride in acetic acid. [1] The compound has attracted much academic interest because it features a fractional metal-metal bond order of 2.5. [2]
The [Ru2(O2CCH3)4+ core adopts the Chinese lantern structure, with four acetate ligands spanning the Ru2 center. The Ru-Ru distance is 228 pm. [3] [4] The [Ru2(O2CCH3)4+ units are linked by bridging chloride ligands.