Identifiers | |
---|---|
3D model (
JSmol)
|
|
3603125 | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.012.803 |
EC Number |
|
28161 | |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
C12H10Zn | |
Molar mass | 219.59 g·mol−1 |
Hazards | |
GHS labelling: | |
Danger | |
H228, H250 | |
P210, P222, P240, P241, P280, P302+P334, P370+P378, P422 | |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Diphenylzinc is an organozinc compound. It is commonly used as the synthetic equivalent of a Ph− synthon. Solvent-free diphenylzinc exists as dimeric PhZn(μ-Ph)2ZnPh molecules in the solid state. [1]
Diphenylzinc is commercially available. It may be prepared by reaction of phenyllithium with zinc bromide: [2]
It may also be prepared by the reaction of phenylmagnesium bromide with zinc chloride or diphenylmercury with zinc metal. [3] [4]
Identifiers | |
---|---|
3D model (
JSmol)
|
|
3603125 | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.012.803 |
EC Number |
|
28161 | |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
C12H10Zn | |
Molar mass | 219.59 g·mol−1 |
Hazards | |
GHS labelling: | |
Danger | |
H228, H250 | |
P210, P222, P240, P241, P280, P302+P334, P370+P378, P422 | |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Diphenylzinc is an organozinc compound. It is commonly used as the synthetic equivalent of a Ph− synthon. Solvent-free diphenylzinc exists as dimeric PhZn(μ-Ph)2ZnPh molecules in the solid state. [1]
Diphenylzinc is commercially available. It may be prepared by reaction of phenyllithium with zinc bromide: [2]
It may also be prepared by the reaction of phenylmagnesium bromide with zinc chloride or diphenylmercury with zinc metal. [3] [4]