| |
Names | |
---|---|
IUPAC name
| |
Preferred IUPAC name
Dihydroxymethylidene | |
Other names
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
MeSH | Dihydroxycarbene |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
C(OH)2 | |
Molar mass | 46.025 g·mol−1 |
Related compounds | |
Related compounds
|
|
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Dihydroxymethylidene or carbonous acid is a chemical compound with formula C(OH)2. It is an unstable tautomer of formic acid. There is no evidence that this compound exists in solution, but the molecule has been detected in the gas phase. [1] Many related carbenes are known, although they are often transient. [2]
Dihydroxymethylidene is produced in the gas phase by high vacuum flash vacuum pyrolysis of oxalic acid:
The species is a bent molecule with an O−C−O angle of 105.6° for the C2v all-trans rotamer. Although stable at 10 K, at higher temperatures it isomerizes to formic acid.
The double ionized ion, CO2−2, is known as the carbonite ion.
| |
Names | |
---|---|
IUPAC name
| |
Preferred IUPAC name
Dihydroxymethylidene | |
Other names
| |
Identifiers | |
3D model (
JSmol)
|
|
ChemSpider | |
MeSH | Dihydroxycarbene |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
C(OH)2 | |
Molar mass | 46.025 g·mol−1 |
Related compounds | |
Related compounds
|
|
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Dihydroxymethylidene or carbonous acid is a chemical compound with formula C(OH)2. It is an unstable tautomer of formic acid. There is no evidence that this compound exists in solution, but the molecule has been detected in the gas phase. [1] Many related carbenes are known, although they are often transient. [2]
Dihydroxymethylidene is produced in the gas phase by high vacuum flash vacuum pyrolysis of oxalic acid:
The species is a bent molecule with an O−C−O angle of 105.6° for the C2v all-trans rotamer. Although stable at 10 K, at higher temperatures it isomerizes to formic acid.
The double ionized ion, CO2−2, is known as the carbonite ion.