6.svg)
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| Names | |
|---|---|
| Other names
hexacarbonyldi-μ-chlorodichlorodiruthenium
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| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.159.029 |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
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| Properties | |
| C6Cl4O6Ru2 | |
| Molar mass | 512.00 g·mol−1 |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Dichlororuthenium tricarbonyl dimer is an organoruthenium compound with the formula [RuCl2(CO)32. A yellow solid, the molecule features a pair of octahedral Ru centers bridged by a pair of chloride ligands. The complex is a common starting material in ruthenium chemistry. [1]
Dichlororuthenium tricarbonyl dimer arises by the carbonylation of a hot solution of ruthenium trichloride in methoxyethanol. [2]
The complex exists in equilibrium with the polymer:
- n [RuCl2(CO)32 → [RuCl2(CO)22n + 2 CO
It reacts with potassium hydroxide in alcohol to give triruthenium dodecacarbonyl.
Dichlororuthenium tricarbonyl dimer reacts with glycine to give tricarbonylchloroglycinatoruthenium(II). [3]
- ^ Haukka, Matti; Kiviaho, Jari; Ahlgren, Markku; Pakkanen, Tapani A. (1995). "Studies on Catalytically Active Ruthenium Carbonyl Bipyridine Systems. Synthesis and Structural Characterization of [Ru(bpy)(CO)2Cl2], [Ru(bpy)(CO)2Cl(C(O)OCH3)], [Ru(bpy)(CO)2Cl]2, and [Ru(bpy)(CO)2ClH] (Bpy = 2,2'-Bipyridine)". Organometallics. 14 (2): 825–833. doi: 10.1021/om00002a033.
- ^ Fauré, Matthieu; Saccavini, Catherine; Lavigne, Guy (2004). Dodecacarbonyltriruthenium. Inorganic Syntheses. Vol. 34. p. 110. doi: 10.1002/0471653683.ch3.
- ^ Clark, James E.; Naughton, Patrick; Shurey, Sandra; Green, Colin J.; Johnson, Tony R.; Mann, Brian E.; Foresti, Roberta; Motterlini, Roberto (2003). "Cardioprotective Actions by a Water-Soluble Carbon Monoxide–Releasing Molecule". Circulation Research. 93 (2): e2-8. doi: 10.1161/01.RES.0000084381.86567.08. PMID 12842916. S2CID 784328.
|
| |
| Names | |
|---|---|
| Other names
hexacarbonyldi-μ-chlorodichlorodiruthenium
| |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.159.029 |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
| Properties | |
| C6Cl4O6Ru2 | |
| Molar mass | 512.00 g·mol−1 |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Dichlororuthenium tricarbonyl dimer is an organoruthenium compound with the formula [RuCl2(CO)32. A yellow solid, the molecule features a pair of octahedral Ru centers bridged by a pair of chloride ligands. The complex is a common starting material in ruthenium chemistry. [1]
Dichlororuthenium tricarbonyl dimer arises by the carbonylation of a hot solution of ruthenium trichloride in methoxyethanol. [2]
The complex exists in equilibrium with the polymer:
- n [RuCl2(CO)32 → [RuCl2(CO)22n + 2 CO
It reacts with potassium hydroxide in alcohol to give triruthenium dodecacarbonyl.
Dichlororuthenium tricarbonyl dimer reacts with glycine to give tricarbonylchloroglycinatoruthenium(II). [3]
- ^ Haukka, Matti; Kiviaho, Jari; Ahlgren, Markku; Pakkanen, Tapani A. (1995). "Studies on Catalytically Active Ruthenium Carbonyl Bipyridine Systems. Synthesis and Structural Characterization of [Ru(bpy)(CO)2Cl2], [Ru(bpy)(CO)2Cl(C(O)OCH3)], [Ru(bpy)(CO)2Cl]2, and [Ru(bpy)(CO)2ClH] (Bpy = 2,2'-Bipyridine)". Organometallics. 14 (2): 825–833. doi: 10.1021/om00002a033.
- ^ Fauré, Matthieu; Saccavini, Catherine; Lavigne, Guy (2004). Dodecacarbonyltriruthenium. Inorganic Syntheses. Vol. 34. p. 110. doi: 10.1002/0471653683.ch3.
- ^ Clark, James E.; Naughton, Patrick; Shurey, Sandra; Green, Colin J.; Johnson, Tony R.; Mann, Brian E.; Foresti, Roberta; Motterlini, Roberto (2003). "Cardioprotective Actions by a Water-Soluble Carbon Monoxide–Releasing Molecule". Circulation Research. 93 (2): e2-8. doi: 10.1161/01.RES.0000084381.86567.08. PMID 12842916. S2CID 784328.