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| Names | |
|---|---|
|
IUPAC name
Carbonyl diazide
| |
| Other names
Carbonyl azide,
Carbonic diazide, Azido ketone | |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
PubChem
CID
|
|
| |
| |
| Properties | |
| CO(N3)2 | |
| Molar mass | 112.052 g·mol−1 |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Carbonyl diazide is a chemical compound with the chemical formula C O( N3)2. In terms of its structure, it can be described as two azide groups −N3 covalently attached to the carbonyl group −C(=O)− by single bonds. It can be prepared by way of the reaction between triphosgene and tetra-n-butylammonium azide, in a dimethyl or diethyl solution. [1]
The first synthesis of carbonyl diazide was reported in 1894, although there have been multiple alternative syntheses since then. [2]
- ^ Nolan, Alex M.; Amberger, Brent K.; Esselman, Brian J.; Thimmakondu, Venkatesan S.; Stanton, John F.; Woods, R. Claude; McMahon, Robert J. (28 September 2012). "Carbonyl Diazide, OC(N3)2: Synthesis, Purification, and IR Spectrum". Inorganic Chemistry. 51 (18): 9486–9851. doi: 10.1021/ic301270b. PMID 22928580. Retrieved 31 October 2023.
- ^ Häring, Andreas P.; Kirsch, Stefan F. (6 November 2015). "Synthesis and Chemistry of Organic Geminal Di- and Triazides". Molecules. 20 (11): 20044–20062. doi: 10.3390/molecules201119675. PMC 6331879. PMID 26561796.
 | This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |
|
| |
| Names | |
|---|---|
|
IUPAC name
Carbonyl diazide
| |
| Other names
Carbonyl azide,
Carbonic diazide, Azido ketone | |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
PubChem
CID
|
|
| |
| |
| Properties | |
| CO(N3)2 | |
| Molar mass | 112.052 g·mol−1 |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Carbonyl diazide is a chemical compound with the chemical formula C O( N3)2. In terms of its structure, it can be described as two azide groups −N3 covalently attached to the carbonyl group −C(=O)− by single bonds. It can be prepared by way of the reaction between triphosgene and tetra-n-butylammonium azide, in a dimethyl or diethyl solution. [1]
The first synthesis of carbonyl diazide was reported in 1894, although there have been multiple alternative syntheses since then. [2]
- ^ Nolan, Alex M.; Amberger, Brent K.; Esselman, Brian J.; Thimmakondu, Venkatesan S.; Stanton, John F.; Woods, R. Claude; McMahon, Robert J. (28 September 2012). "Carbonyl Diazide, OC(N3)2: Synthesis, Purification, and IR Spectrum". Inorganic Chemistry. 51 (18): 9486–9851. doi: 10.1021/ic301270b. PMID 22928580. Retrieved 31 October 2023.
- ^ Häring, Andreas P.; Kirsch, Stefan F. (6 November 2015). "Synthesis and Chemistry of Organic Geminal Di- and Triazides". Molecules. 20 (11): 20044–20062. doi: 10.3390/molecules201119675. PMC 6331879. PMID 26561796.
|
| This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |