From Wikipedia, the free encyclopedia
Bromo(tetrahydrothiophene)gold(I)
Identifiers
3D model ( JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C4H8S.Au.BrH/c1-2-4-5-3-1;;/h1-4H2;;1H/q;+1;/p-1
    Key: DVTPJQDAZYEPPF-UHFFFAOYSA-M
  • Br[Au-][S+]1CCCC1
Properties
C4H8AuBrS
Molar mass 365.04 g·mol−1
Related compounds
Related compounds
chloro(tetrahydrothiophene)gold(I), chloro(dimethyl sulfide)gold(I)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY  verify ( what is checkY☒N ?)

Bromo(tetrahydrothiophene)gold(I) is a coordination complex of gold. It is related to the more commonly used chloro(tetrahydrothiophene)gold(I). Similarly, the tetrahydrothiophene ligand is labile and is readily substituted with other stronger ligands, to give linear gold bromide complexes.

This compound may be prepared by reaction of tetrabromoauric acid (formed from tetrachloroauric acid and hydrobromic acid) with tetrahydrothiophene. [1]

References

  1. ^ Eiter, Lauren C.; Hall, Nathan W.; Day, Cynthia S.; Saluta, Gilda; Kucera, Gregory L.; Bierbach, Ulrich (2009). "Gold(I) Analogues of a Platinum–Acridine Antitumor Agent are only Moderately Cytotoxic but Show Potent Activity Against Mycobacterium Tuberculosis". Journal of Medicinal Chemistry. 52 (21): 6519–22. doi: 10.1021/jm9012856. PMC  3176588. PMID  19803526.
From Wikipedia, the free encyclopedia
Bromo(tetrahydrothiophene)gold(I)
Identifiers
3D model ( JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C4H8S.Au.BrH/c1-2-4-5-3-1;;/h1-4H2;;1H/q;+1;/p-1
    Key: DVTPJQDAZYEPPF-UHFFFAOYSA-M
  • Br[Au-][S+]1CCCC1
Properties
C4H8AuBrS
Molar mass 365.04 g·mol−1
Related compounds
Related compounds
chloro(tetrahydrothiophene)gold(I), chloro(dimethyl sulfide)gold(I)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY  verify ( what is checkY☒N ?)

Bromo(tetrahydrothiophene)gold(I) is a coordination complex of gold. It is related to the more commonly used chloro(tetrahydrothiophene)gold(I). Similarly, the tetrahydrothiophene ligand is labile and is readily substituted with other stronger ligands, to give linear gold bromide complexes.

This compound may be prepared by reaction of tetrabromoauric acid (formed from tetrachloroauric acid and hydrobromic acid) with tetrahydrothiophene. [1]

References

  1. ^ Eiter, Lauren C.; Hall, Nathan W.; Day, Cynthia S.; Saluta, Gilda; Kucera, Gregory L.; Bierbach, Ulrich (2009). "Gold(I) Analogues of a Platinum–Acridine Antitumor Agent are only Moderately Cytotoxic but Show Potent Activity Against Mycobacterium Tuberculosis". Journal of Medicinal Chemistry. 52 (21): 6519–22. doi: 10.1021/jm9012856. PMC  3176588. PMID  19803526.

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