From Wikipedia, the free encyclopedia
Americium(III) iodide
Names
IUPAC name
Americium(III) iodide
Other names
Americium triiodide
Identifiers
3D model ( JSmol)
PubChem CID
  • InChI=1S/Am.3HI/h;3*1H/p-3
    Key: YYYYEVJUHBVYGQ-UHFFFAOYSA-K
  • [I-].[I-].[I-].[Am]
Properties
AmI3
Molar mass 624 g·mol−1
Related compounds
Other anions
Americium(III) fluoride
Americium(III) chloride
Americium(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Americium(III) iodide or americium triiodide is the chemical compound, a salt composed of americium and iodine with the formula AmI3.

Preparation

Americium(III) iodide can be prepared by reacting americium(III) chloride with ammonium iodide: [2]

AmCl3 + 3 NH4I → AmI3 + 3NH4Cl

Properties

Americium(III) iodide takes the form of yellow crystals. The crystal form is orthorhombic. It melts around 960 °C. The density is 6.9 g/cm3. [1] The compound consists of Am3+ and I ions. It crystallizes in the trigonal crystal system in the space group R3 (space group no. 148) with the lattice parameters a = 742 pm and c = 2055 pm and six formula units per unit cell. Its crystal structure is isotypic with bismuth(III) iodide. [2] [3]

References

  1. ^ a b Haynes, William M. (2011). CRC Handbook of Chemistry and Physics, 92nd Edition. CRC Press. pp. 4–46. ISBN  9781439855126.
  2. ^ a b Asprey, L. B.; Keenan, T. K.; Kruse, F. H. (Jul 1965). "Crystal Structures of the Trifluorides, Trichlorides, Tribromides, and Triiodides of Americium and Curium". Inorganic Chemistry. 4 (7): 985–986. doi: 10.1021/ic50029a013. ISSN  0020-1669. S2CID  96551460.
  3. ^ Gmelins Handbuch der anorganischen Chemie, System No. 71, Transurane, Teil C, pp. 154.


From Wikipedia, the free encyclopedia
Americium(III) iodide
Names
IUPAC name
Americium(III) iodide
Other names
Americium triiodide
Identifiers
3D model ( JSmol)
PubChem CID
  • InChI=1S/Am.3HI/h;3*1H/p-3
    Key: YYYYEVJUHBVYGQ-UHFFFAOYSA-K
  • [I-].[I-].[I-].[Am]
Properties
AmI3
Molar mass 624 g·mol−1
Related compounds
Other anions
Americium(III) fluoride
Americium(III) chloride
Americium(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Americium(III) iodide or americium triiodide is the chemical compound, a salt composed of americium and iodine with the formula AmI3.

Preparation

Americium(III) iodide can be prepared by reacting americium(III) chloride with ammonium iodide: [2]

AmCl3 + 3 NH4I → AmI3 + 3NH4Cl

Properties

Americium(III) iodide takes the form of yellow crystals. The crystal form is orthorhombic. It melts around 960 °C. The density is 6.9 g/cm3. [1] The compound consists of Am3+ and I ions. It crystallizes in the trigonal crystal system in the space group R3 (space group no. 148) with the lattice parameters a = 742 pm and c = 2055 pm and six formula units per unit cell. Its crystal structure is isotypic with bismuth(III) iodide. [2] [3]

References

  1. ^ a b Haynes, William M. (2011). CRC Handbook of Chemistry and Physics, 92nd Edition. CRC Press. pp. 4–46. ISBN  9781439855126.
  2. ^ a b Asprey, L. B.; Keenan, T. K.; Kruse, F. H. (Jul 1965). "Crystal Structures of the Trifluorides, Trichlorides, Tribromides, and Triiodides of Americium and Curium". Inorganic Chemistry. 4 (7): 985–986. doi: 10.1021/ic50029a013. ISSN  0020-1669. S2CID  96551460.
  3. ^ Gmelins Handbuch der anorganischen Chemie, System No. 71, Transurane, Teil C, pp. 154.



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