Names | |
---|---|
Preferred IUPAC name
Adamantan-2-one | |
Other names
Tricyclo[3.3.1.13,7]decanone
2-Adamantanone | |
Identifiers | |
3D model (
JSmol)
|
|
ChEBI | |
ChEMBL | |
ChemSpider | |
DrugBank | |
ECHA InfoCard | 100.010.772 |
EC Number |
|
122962 | |
PubChem
CID
|
|
UNII | |
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
C10H14O | |
Molar mass | 150.221 g·mol−1 |
Appearance | white solid |
Melting point | 270 °C (518 °F; 543 K) |
Hazards | |
GHS labelling: | |
Danger | |
H301, H315, H318, H410 | |
P264, P270, P273, P280, P301+P310, P302+P352, P305+P351+P338, P310, P321, P330, P332+P313, P362, P391, P405, P501 | |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Adamantanone is the ketone of adamantane. A white solid, it is prepared by oxidation of adamantane. [1] It is a precursor to several adamantane derivatives. [2]
Adamantanone and some related polycyclic ketones, are reluctant to form enolates. This barrier arises because the resulting carbanion cannot exist in conjugation with the carbonyl pi-bond. [3] [4] [5]
Names | |
---|---|
Preferred IUPAC name
Adamantan-2-one | |
Other names
Tricyclo[3.3.1.13,7]decanone
2-Adamantanone | |
Identifiers | |
3D model (
JSmol)
|
|
ChEBI | |
ChEMBL | |
ChemSpider | |
DrugBank | |
ECHA InfoCard | 100.010.772 |
EC Number |
|
122962 | |
PubChem
CID
|
|
UNII | |
CompTox Dashboard (
EPA)
|
|
| |
| |
Properties | |
C10H14O | |
Molar mass | 150.221 g·mol−1 |
Appearance | white solid |
Melting point | 270 °C (518 °F; 543 K) |
Hazards | |
GHS labelling: | |
Danger | |
H301, H315, H318, H410 | |
P264, P270, P273, P280, P301+P310, P302+P352, P305+P351+P338, P310, P321, P330, P332+P313, P362, P391, P405, P501 | |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
|
Adamantanone is the ketone of adamantane. A white solid, it is prepared by oxidation of adamantane. [1] It is a precursor to several adamantane derivatives. [2]
Adamantanone and some related polycyclic ketones, are reluctant to form enolates. This barrier arises because the resulting carbanion cannot exist in conjugation with the carbonyl pi-bond. [3] [4] [5]