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| Names | |
|---|---|
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Preferred IUPAC name
1,5-Dithiocane | |
| Other names
DTO
| |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
| Properties | |
| C6H12S2 | |
| Molar mass | 148.28 g·mol−1 |
| Appearance | colorless liquid |
| Melting point | −15 °C (5 °F; 258 K) |
| Boiling point | 245–6 °C (473–43 °F; 518–279 K) |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
1,5-Dithiacyclooctane (DTCO) is an organosulfur compound with the formula (CH2CH2)CH2S)2. This cyclic di thioether is a colorless oil that is soluble in polar solvents. It forms a variety of transition metal thioether complexes.
DTO can be oxidized to the bicyclic dication. [1]
PdCl2_(VIVXUT).png)
DTCO was first prepared in 4% yield by di alkylation of 1,3-propanedithiol with 1,3-dibromopropane. [2]
- ^ Musker, W. Kenneth (1992). "Coordination Chemistry of Bidentate Medium Ring Ligands (Mesocycles)". Coordination Chemistry Reviews. 117: 133–57. doi: 10.1016/0010-8545(92)80022-J.
- ^ Meadow, J. R.; Reid, E. E. (1934). "Ring compounds and polymers from polymethylene dihalides and dimercaptans". J. Am. Chem. Soc. 56 (10): 2177–2180. doi: 10.1021/ja01325a058.
|
| |
| Names | |
|---|---|
|
Preferred IUPAC name
1,5-Dithiocane | |
| Other names
DTO
| |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
PubChem
CID
|
|
CompTox Dashboard (
EPA)
|
|
| |
| |
| Properties | |
| C6H12S2 | |
| Molar mass | 148.28 g·mol−1 |
| Appearance | colorless liquid |
| Melting point | −15 °C (5 °F; 258 K) |
| Boiling point | 245–6 °C (473–43 °F; 518–279 K) |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
1,5-Dithiacyclooctane (DTCO) is an organosulfur compound with the formula (CH2CH2)CH2S)2. This cyclic di thioether is a colorless oil that is soluble in polar solvents. It forms a variety of transition metal thioether complexes.
DTO can be oxidized to the bicyclic dication. [1]
DTCO was first prepared in 4% yield by di alkylation of 1,3-propanedithiol with 1,3-dibromopropane. [2]
- ^ Musker, W. Kenneth (1992). "Coordination Chemistry of Bidentate Medium Ring Ligands (Mesocycles)". Coordination Chemistry Reviews. 117: 133–57. doi: 10.1016/0010-8545(92)80022-J.
- ^ Meadow, J. R.; Reid, E. E. (1934). "Ring compounds and polymers from polymethylene dihalides and dimercaptans". J. Am. Chem. Soc. 56 (10): 2177–2180. doi: 10.1021/ja01325a058.