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| Names | |
|---|---|
| Other names
troticene
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| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
PubChem
CID
|
|
| |
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| Properties | |
| C12H12Ti | |
| Molar mass | 204.095 g·mol−1 |
| Appearance | blue solid |
| Density | 1.40 g/cm3 |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
(Cycloheptatrienyl)(cyclopentadienyl)titanium is an organotitanium compound with the formula Ti(C7H7)(C5H5). It is a blue, diamagnetic, sublimable solid that is sensitive toward air. The structure has been confirmed by X-ray crystallography. [1] This sandwich complex features cyclopentadienyl and cycloheptatrienyl ligands bound to titanium. The Ti-C distances are all within a narrow range near 2.35 Å.
The complex can be prepared by the reaction of titanocene dichloride, butyllithium, and cycloheptatriene. [2]
See also
References
- ^ Zeinstra, J.D.; De Boer, J.L. (1973). "Structure of Cyclopentadienylcycloheptatrienyl-titanium". Journal of Organometallic Chemistry. 54: 207–211. doi: 10.1016/S0022-328X(00)85010-X.
- ^ Camargo, Luana C.; Briganti, Matteo; Santana, Francielli S.; Stinghen, Danilo; Ribeiro, Ronny R.; Nunes, Giovana G.; Soares, Jaísa F.; Salvadori, Enrico; Chiesa, Mario; Benci, Stefano; Torre, Renato; Sorace, Lorenzo; Totti, Federico; Sessoli, Roberta (2021). "Exploring the Organometallic Route to Molecular Spin Qubits: The [Cp Ti(cot)] Case". Angewandte Chemie International Edition. 60 (5): 2588–2593. doi: 10.1002/anie.202009634. hdl: 2318/1765157. PMID 33051985. S2CID 222351619.
|
| |
| Names | |
|---|---|
| Other names
troticene
| |
| Identifiers | |
3D model (
JSmol)
|
|
| ChemSpider | |
PubChem
CID
|
|
| |
| |
| Properties | |
| C12H12Ti | |
| Molar mass | 204.095 g·mol−1 |
| Appearance | blue solid |
| Density | 1.40 g/cm3 |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
(Cycloheptatrienyl)(cyclopentadienyl)titanium is an organotitanium compound with the formula Ti(C7H7)(C5H5). It is a blue, diamagnetic, sublimable solid that is sensitive toward air. The structure has been confirmed by X-ray crystallography. [1] This sandwich complex features cyclopentadienyl and cycloheptatrienyl ligands bound to titanium. The Ti-C distances are all within a narrow range near 2.35 Å.
The complex can be prepared by the reaction of titanocene dichloride, butyllithium, and cycloheptatriene. [2]
See also
References
- ^ Zeinstra, J.D.; De Boer, J.L. (1973). "Structure of Cyclopentadienylcycloheptatrienyl-titanium". Journal of Organometallic Chemistry. 54: 207–211. doi: 10.1016/S0022-328X(00)85010-X.
- ^ Camargo, Luana C.; Briganti, Matteo; Santana, Francielli S.; Stinghen, Danilo; Ribeiro, Ronny R.; Nunes, Giovana G.; Soares, Jaísa F.; Salvadori, Enrico; Chiesa, Mario; Benci, Stefano; Torre, Renato; Sorace, Lorenzo; Totti, Federico; Sessoli, Roberta (2021). "Exploring the Organometallic Route to Molecular Spin Qubits: The [Cp Ti(cot)] Case". Angewandte Chemie International Edition. 60 (5): 2588–2593. doi: 10.1002/anie.202009634. hdl: 2318/1765157. PMID 33051985. S2CID 222351619.